UNIVERSITY OF WASHINGTON CTD/GTD DATA FOR HALE-ALOHA 1, 2 AND 3 12 JAN 1997 to 13 MAY 1998 During the period of 12 January 1997 through 13 May 1998, Steven Emerson and Charles Stump of the University of Washington deployed a CTD/GTD device at the HALE-ALOHA mooring site of the University of Hawaii. This was done in association with Dave Karl and Terry Houlihan of UH. This CTD/GTD device was placed at 50 m depth in each mooring cycle. The device consists of a Seabird Seacat 16DO CTD capable of measuring temperature, salinity, pressure and oxygen. Attached to this CTD is a gas tension device (GTD) designed and built by Dr. Bruce Johnson at Dalhousie University in Halifax, Nova Scotia, Canada. The GTD device measures total gas pressure across a silicone membrane. A pinhole opening below the membrane is connected to a Parascientific pressure sensor. Changes in partial pressure alter the sensor frequency. These frequency changes, as well as temperature, salinity, pressure and oxygen are stored in the Seacat's memory until recovery. Upon recovery, the data is downloaded, processed and converted to scientific units using the calibration values of the Seabird CTD and the GTD. The CTD/GTD data is reported out in the following units: temperature - Deg C salinity - o/oo Sigma t - kg/m3 (calculated) pressure - mbars oxygen - umol/l GTD - mbars During the course of each mooring, samples were taken at Station 8 near the HALE-ALOHA mooring site to calibrate the CTD/GTD. These samples were taken at the time of deployment and several times during the course of each mooring cycle. Samples were obtained using the University of Hawaii rosette and CTD. The bottles were sampled for oxygen determined by Winkler titration and O2/Ar, O2/N2 and N2/Ar ratios determined by mass spectrometry. CTD values from these casts were used to confirm the temperature and salinity data from the UW CTD. The Winkler oxygen results were used to calibrate the oxygen values registered by the UW CTD. The ratios obtained by mass spectrometry were used to calculate concentrations of N2 and Ar based on the Winkler O2. The concentration of N2 is calculated from the measured concentration of O2, [O2], and the total gas pressure, P, assuming the partial pressures of argon, pAr, and water, pH2O, are at saturation equilibrium and that the atmospheric pCO2 is negligible. [N2] = { Sigma P - [O2] / SO2 - (XAr + XH2O) Patm} SN2 ; where S is the solubility which is a function of temperature; X is the mole fraction of the gas in the atmosphere and Patm is the atmospheric pressure. The latter value was obtained from NODC Buoy 51001 for the calculation. This calculated N2 concentration is then compared to the samples obtained from Station 8.