Hawaii Ocean Time-series (HOT)
in the School of Ocean and Earth Science and Technology at the University of Hawai'i

Dissolved Oxygen

Oxygen Titration
FTP View Data
To assist in the interpretation of the data, it can be displayed using the Hawaii Ocean Time-series Data Organization & Graphical System (HOT-DOGS©).

Analytical Method

Dissolved oxygen samples were collected and analyzed using a computer controlled potentiometric end-point titration procedure as described in Tupas et al. (1997). As in previous years we measured, using a calibrated digital thermistor, the temperature of the seawater sample at the time the iodine flask was filled. This was done to evaluate the magnitude of sample temperature error which affects the calculation of oxygen concentrations in units of µmol/kg. The Figure below (upper panel) shows a plot of the difference between on-deck sample temperature and potential temperature, computed from the in situ temperature measured at the time of bottle trip, versus pressure. The lower panel of the same figure shows a plot of the difference between oxygen concentration using the sample temperature and potential temperatures versus pressure. The depth dependent variability in Δ-oxygen is a result of: 1) bottle warming as the rosette is brought up through the water column 2) warm air entering the niskin bottle as samples are being taken and 3) evaporative cooling that occurs while on-deck as bottles are waiting to be sampled.

Sample temperature difference

Precision of the Winkler titration method is presented in the Table below. The pooled annual mean CV of our oxygen analyses in 2015 was 0.14%. It was calculated by averaging the mean CV of N-triplicate samples on each cruise. Oxygen concentrations measured over the 27 years of the program are plotted at three constant potential density horizons in the deep ocean along with their mean and 95% confidence intervals (Figure 12). These results indicate that analytical consistency has been maintained over the past 27 years of the HOT program.


Cruise mean CV
(%)
mean SD
(µmol/l)
N
269 0.23 0.394 8
270 0.15 0.271 8
271 0.11 0.182 8
272 0.12 0.215 8
273 0.10 0.194 8
274 0.14 0.240 8
275 0.13 0.228 8
276 0.12 0.257 2
277 0.18 0.307 8
278 0.12 0.226 8
279 0.12 0.219 7
Mean 0.14 0.249 11

Results

Figure 13 and Figure 14 show contoured time-series data for oxygen in the upper 1000 dbar at Station ALOHA. The oxygen data show a strong oxycline between 400 and 625 dbar (26.25-27.0 σθ), and an oxygen minimum centered near 800 dbar (27.2 σθ). Recurrent drops in the oxygen concentration can be seen throughout the time-series between 25 and 26.25 σθ. These features are accompanied by a decrease in salinity and an increase in the nutrient concentration. The anomalous low oxygen centered at 400 dbar in early 2001 is due to an eddy observed during HOT-122. A similar low oxygen feature is centered at 350 dbar in May 2012 (HOT-241).

The oxygen minimum exhibits some interannual variability, with values less then 30 µmol kg-1 appearing frequently during the time-series. This variability can be seen in a plot of the mean oxygen in the intermediate waters spanning the oxygen minimum (27-27.8 σθ, Figure 31). Superimposed on this variability is a general trend towards lower oxygen values from 1989 throughout 1996, with an increase between 1997 and 2000, followed by a shap decrease during 2001, and reaching record low values during the second half of 2002, and increasing sharply during 2003 and 2004 to reach record high values in mid-2004, decreasing again to values close to those in 2002 by the end of 2005 and in the Fall of 2007. An increasing trend started in late 2005 to reach record high values in mid-2010 to then start decreasing throughout late 2012 and then by a sharp increase to record values in 2014 and a decrease during 2015.

The surface layer shows a seasonality in oxygen concentrations, with highest values in the winter. This pattern corresponds roughly to the minimum in surface layer temperature (Figure 1).

A contour plot of dissolved oxygen concentration in the upper 200 dbar of the water column from 1988-2015 based on analyses of water samples collected at discrete depths is shown in Figure 15. Dissolved oxygen shows a maximum between 60 and 110m depth that develops during the summer-fall. This maximum, presumably of biological origin, is typically eroded during the winter.